酸溶——催化极谱法测定地质样品中的钨、钼

本文采用混合酸溶解样品,对影响催化体系稳定的酸度、温度和不同反应时间的因素分别进行了对比试验,确定催化体系相对稳定的最佳条件,经过大量样品的分析验证,分析方法可靠。     

基于GPS的短基线定向测量及精度分析

介绍了利用GPS载波相位测量技术进行短基线定向的基本方法,推导了估计GPS短基线定向的精度公式,得到了对于边长400～700 m的基线可以达到±(1"～2")的方位精度.     

南海西部浮游有孔虫记录的MIS 3期表层海洋环境变化

对南海西部越南岸外上升流区17954-2站浮游有孔虫属种组合变化、浮游有孔虫氧同位素、AMS14C测年的分析以及浮游有孔虫表层海水温度、温跃层转换函数的研究结果表明:在MIS3期,南海西部表层海水温度大体呈现暖-冷-暖的变化趋势;温跃层深度由浅到深阶段性变化;短时间尺度上温度与温跃层发生幅度较大的快速变化。暖事件（IS）对应于浮游有孔虫暖水种、混合层属种含量的增加,冷水种、温跃层属种含量的减少以及冬夏SST的升高;冷事件则与之相反。表层海水生产力亦大致呈现3个阶段（61～51ka,51～42ka和42～32ka）的变化,在千年尺度的快速气候事件中,暖事件对应浮游有孔虫生产力属种含量降低,冷事件对应升高。此外,在MIS3内部分暖事件（IS6和IS11～13）表现出表层海水温度降低,温跃层深度变浅和表层海水生产力升高的状况,表明该区此时上升流的存在,其形成原因推测是由于东亚夏季风加强的结果。     

火山沉积岩及其矿床研究中伽马测井曲线解释的误区

根据酸性凝灰岩和酸性火山事件粘土岩的自然伽马测井曲线,对当前流传的"沉积岩层的放射性强度(或放射性核素的含量)随泥质含量的增加而增高"的概念和用自然伽马值及经验公式求泥质含量提出质凝。酸性凝灰岩的自然伽马曲线有高异常响应,若解释为泥岩显然是误解,故将沉积岩伽马曲线高异常一律解释为泥岩是片面的。各类火山事件粘土岩的伽马值相差悬殊,但其泥质含量几乎相等,用它们的伽马值计算泥质含量误差甚大。最后对铝土矿层的伽马曲线稍加解释,指出核测井应用的远景。     

国内外城市雨水径流水质的研究

综合国内外综合资料,对城市不同建筑材料屋面和不同路面的雨水径流水质特征进行了对比分析,阐明了影响城市雨水径流水质的三大因素,并论述了城市雨水收集利用的现实意义。     

Study on rain-runoff process in the peripheral mountainous area of the Sichuan Basin

Studies on rain-runoff process in the peripheral mountainous area of the Sichuan Basin, which is regarded as a key ecological shelter, will contribute to flood control and environmental protection for the Upper Yangtze River Basin. In two typical catchments--the Fujiang River Catchment and the Wujiang River Catchment, rainfall simulations have been conducted to study the rain-runoff processes of yellow soil and limestone soil in three types of land use--forestland, farmland and grassland. Results showed that （1） within the same rainfall process, overland flow occurs first on farmland, then on grassland, and finally on forestland; （2） soil surface coverage has a great impact on the occurrence and amount of overland flow. The runoff amount can increase 2-4 times after the coverage is removed; （3） the infiltration before the occurrence of overland flow will decrease because of higher gravel contents of soil, but it takes no effect on infiltration once overland flow becomes stable; （4） the runoff coefficient of the limestone soil forestland is greater than that of the yellow soil forest land, but less than that of the farmland; （5） three empirical infiltration models, including Horton＇ model, Kostiakov＇ model, and modified Kostiakov＇ model, were compared by using the observed results under rainfall simulation. The results showed that the Kostiakov＇ model performed better than both the Horton＇ model and modified Kostiakov model. According to the results of this research, the Kostiakov＇s model can be used to simulate rainfall infiltration when water erosion is modeled in the peripheral mountainous area of the Sichuan Basin.     

鄂尔多斯地块早白垩世构造-热事件:杭锦旗玄武岩的Ar-Ar年代学证据

在鄂尔多斯地块北部杭锦旗黑石头沟,于下白垩统砂岩之上发现了一层玄武岩。其SiO2(46.93%)较低而碱含量(K2O+Na2O=6.21%)较高,组合指数σ=8.0,含标准矿物Ne,属于碱性橄榄玄武岩。Ar-Ar激光阶段加热定年结果表明,该玄武岩具有126.2±0.4Ma的Ar-Ar年龄。年龄数据表明杭锦旗黑石头沟玄武岩形成于早白垩世,反映鄂尔多斯地块在早白垩世发生了一次构造-岩浆-热事件,这与华北、乃至整个中国东部在早白垩世发生了较普遍的构造-岩浆-热事件具有一致性。这次构造-岩浆-热事件可能引起深部流体自地下深部上涌及在地块内部运移,为各种成矿元素的迁移、沉淀、富集和成矿创造了合适条件。     

矿井涌水量混沌时间序列分析与预测

矿井地下水系统是个非线性系统,由于地下水系统的复杂性,很难完全确定影响矿井涌水量的因素,因此传统的矿井涌水预测表现出较大的局限性。而混沌时间序列分析能够利用单变量处理方法,分析矿井地下水系统中,由于多因素耦合作用所产生的矿井涌水量时间序列。通过对某矿区1985年9月至2005年2月矿井涌水量时间序列资料的分析,显示矿井涌水量时间序列具有混沌特征;通过对比预测值和实测值,表明预测精度高。因此,混沌时间序列分析方法用于矿井涌水量预测是可行的。     

GNSS three carrier ambiguity resolution using ionosphere-reduced virtual signals

This paper presents a general modeling strategy for ambiguity resolution (AR) and position estimation (PE) using three or more phase-based ranging signals from a global navigation satellite system (GNSS). The proposed strategy will identify three best “virtual” signals to allow for more reliable AR under certain observational conditions characterized by ionospheric and tropospheric delay variability, level of phase noise and orbit accuracy. The selected virtual signals suffer from minimal or relatively low ionospheric effects, and thus are known as ionosphere-reduced virtual signals. As a result, the ionospheric parameters in the geometry-based observational models can be eliminated for long baselines, typically those of length tens to hundreds of kilometres. The proposed modeling comprises three major steps. Step 1 is the geometry-free determination of the extra-widelane (EWL) formed between the two closest L-band carrier measurements, directly from the two corresponding code measurements. Step 2 forms the second EWL signal and resolves the integer ambiguity with a geometry-based estimator alone or together with the first EWL. This is followed by a procedure to correct for the first-order ionospheric delay using the two ambiguity-fixed widelane (WL) signals derived from the integer-fixed EWL signals. Step 3 finds an independent narrow-lane (NL) signal, which is used together with a refined WL to resolve NL ambiguity with geometry-based integer estimation and search algorithms. As a result, the above two AR processes performed with WL/NL and EWL/WL signals respectively, either in sequence or in parallel, can support real time kinematic (RTK) positioning over baselines of tens to hundreds of kilometres, thus enabling centimetre-to-decimentre positioning at the local, regional and even global scales in the future.     

描述岩石粘弹性固体性质的开尔文模型

大多数固体材料都具有弹性,但真实的固体却极少严格遵从弹性的虎克定律。这些固体材料的变形往往有对时间的依赖性,这种性质是流变学研究的内容。岩石是自然界最普遍的固体,它的力学性质在通常条件下可用虎克定律作精确的描述,而在漫长的地质过程中,岩石的流变特征就逐渐显现出来。地质作用越缓慢,岩石对变形时间的依赖性越明显。为精确描述岩石在地质过程的力学性质,流变学方法被引入地质学。笔者已经介绍过描述"牛顿流体"的马克斯威尔流变模型,文中介绍描述粘弹性固体的开尔文流变模型。和马克斯威尔模型一样,开尔文模型也是流变学的基本模型,它是由一个弹性元件和一个阻尼元件并联而成。文中给出开尔文模型的本构关系和地质应用的简介。